Green dye.



UNITED STATES PATENT OFFICE.

ALBERT I-IERRMANN, OF HGGHST-ON-THE-MAIN, GEEMAN Y, ASSIGNOR TO THE FARBIVERKE, VORMALS MEISTER, LUCIUS & BRUNING, OF SAME PLACE.

GREEN DYE.

SPECIFICATION forming part of Letters Patent No. 639,977, dated December 26, 1899.

Original application filed December 12, 1898, Serial No. 699,022. Divided and this application filed June 24,1899. Serial No. 721,688. (No specimens.)

To all whom it may concern.-

Be it known that I, ALBERT HERRMANN, Ph. D., a citizen of the Empire of Germany, residing at Hochst-on-the-Main, Germany, 5 have invented certain new and useful Improvements in the Manufacture of Green Dyestuffs, (this being a divisional application of Letters Patent N 0. 630,224, dated August 1, 1899,) of which the following is a specification. I0 I have found that by adhering to appropriate conditions naphthalenedis'ulfonio acids may be condensed with tetralkyldiamidobenzhydrols in quantity into leucodisulfonic acids, and, further, that these leucodisulfonic I 5 acids yield, when oxidized, new dyestuffs which, besides being fast to washing and light, dye very evenly in an acid-bath.

I illustrate my process by the following example: Twenty-seven kilograms of tetrame- 2o thyldiamidobenzhydrol and thirty-nine kilograms of the sodium salt of 2.7 naphthalenedisulfonic acid are well mixed, and the mixture is run into two hundred kilograms of monohydrate sulfuric acid while well stirring. 25 The thickened mass thus resulting is then heated in a boiling-waterbath until a sample of it is clearly soluble in diluted ammoniathat is to say, till all hydrol has disappeared. This takes place after from five to six hours. 0 The product of reaction is poured into water and transformed in the usual manner into the calcium or sodium salt. For the subsequent oxidation, to a solution of five kilograms of the leuco salt thus obtained in about forty liters of water is added the calculated quan- 3 5 tity of sulfuric acid, and this liquid, while well stirring, is poured into 2.04. kilograms of peroxid of lead mixed with water. The sulfate of lead is then filtered 0E, and the dye solution is evaporated to dryness. 0

Having now described my invention, what I claim is As a new product the dyestuff obtained by condensing tetralkyldiamidobenzhydrol with 2.7 naphthalenedisulfouic acid and by oxidiz- 4 5 ing the resulting leuco compound, the dyestufE being a copper-red powder of metallic luster, easily soluble in water with a green color, soluble with difliculty in alcohol, insoluble in benzene,dyein g wool in an acid-bath 50 an even green fast to washing and light, having the probable constitution:-

In testimony that I claim the foregoing as my invention I have signed my name in presence of two subscribing witnesses.

- ALBERT HERRMANN.

Witnesses:

HEINRICH HAHN, ALFRED BRISBOIS. 

